Reducing filament evaporation
One of the problems of the standard electric light bulb is evaporation of the filament. Small variations in resistivity along the filament cause “hot spots” to form at points of higher resistivity ; a variation of diameter of only 1% will cause a 25% reduction in service life. The hot spots evaporate faster than the rest of the filament, increasing resistance at that point—a positive feedback which ends in the familiar tiny gap in an otherwise healthy-looking filament. Irving Langmuir found that an inert gas, instead of vacuum, would retard evaporation. General service incandescent light bulbs over about 25 watts in rating are now filled with a mixture of mostly argon and some nitrogen, or sometimes krypton.[50] Xenon gas, much more expensive, is used occasionally in small bulbs, such as those for flashlights. Since a filament breaking in a gas-filled bulb can form an electric arc which may spread between the terminals and draw very heavy current, intentionally thin lead-in wires or more elaborate protection devices are therefore often used as fuses built into the light bulb. More nitrogen is used in higher-voltage lamps to reduce the possibility of arcing.
During ordinary operation, the tungsten of the filament evaporates; hotter, more-efficient filaments evaporate faster. Because of this, the lifetime of a filament lamp is a trade-off between efficiency and longevity. The trade-off is typically set to provide a lifetime of several hundred to 2,000 hours for lamps used for general illumination. Theatrical, photographic, and projection lamps may have a useful life of only a few hours, trading life expectancy for high output in a compact form. Long-life general service lamps have lower efficiency but are used where the cost of changing the lamp is high compared to the value of energy used.
Filament notching describes another phenomenon that limits the life of lamps. Lamps operated on direct current develop random stair-step irregularities on the filament surface, reducing the cross section and further increasing heat and evaporation of tungsten at these points. In small lamps operated on direct current, lifespan may be cut in half compared to AC operation. Different alloys of tungsten and rhenium can be used to counteract the effect.
If a light bulb envelope leaks, the hot tungsten filament reacts with air, yielding an aerosol of brown tungsten nitride, brown tungsten dioxide, violet-blue tungsten pentoxide, and yellow tungsten trioxide which then deposits on the nearby surfaces or the bulb interior.